Huang Group
School of Chemical Biology & Biotechnology

Chengming Wang’s paper has been published in Angew. Chem.Int. Ed.! Congratulations!

时间:2013-04-03

ncontentRhodium(III)-Catalyzed CH Activation of Arenes Using a Versatile and Removable Triazene Directing Group

Chengming Wang, Hu Chen, Zhaofeng Wang, Jiean Chen and Yong Huang*.

Angew. Chem. Int. Ed.201251, 7242-7245(cover).

Diverse opportunities: A Rhodium(III)-catalyzed ortho-selective olefination of arenes using a novel triazene as a directing group is reported. This method exhibits substantial post-functionalization synthetic versatility, overcoming a vital limitation in sp2C-H activation/functionalization products: restrictedstructural diversity