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Li group published article on Angew Chem Int Ed about a study of an in tether chiral center modulates the helicity cell permeabilityand target binding affinity of a peptide

The addition of a precisely positioned chiral center in the tether of a constrained peptide is reported, yielding two separable peptide diastereomers with significantly different helicity, as supported by circular dichroism (CD) and NMR spectroscopy. Single crystal X-ray diffraction analysis sugg...

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