Wang’s work has been published in Chemical Communications! Congratulations!
时间:2016-07-07
Decarboxylative Csp3–Csp3 coupling for benzylation of unstable ketone enolates: synthesis of p-(acylethyl)phenols
Sasa Wang, Xinzheng Chen, Qiaoqiao Ao, Huifei Wang* and Hongbin Zhai*
Chem. Commun., 2016, Advance Article
DOI: 10.1039/C6CC03835B
A new decarboxylative Csp3–Csp3 coupling approach for the benzylation of ketone enolates has been developed. A variety of raspberry ketone derivatives were conveniently synthesized in good to excellent yields under mild conditions. A crossover reaction shed light on the mechanism of this tandem reaction.