116.Synthesis of Substituted Benzoxacycles via a Pd(II)-Catalyzed Intramolecular Arylation Reaction of Allylic Alcohols-YANG Group

116.Synthesis of Substituted Benzoxacycles via a Pd(II)-Catalyzed Intramolecular Arylation Reaction of Allylic Alcohols

Jingjie Li, Ceheng Tan, Xinpeng Mu, Jianxian Gong*, Zhen Yang*

Chin. J. Chem. 2017, 35, 562

Herein a Pd-catalyzed intramolecular allylation reaction of unprotected allylic alcohols was developed, and the reaction proceeded through a Pd(II)-mediated allylic carbocation species formation, followed by a Friedel-Crafts type annulation to afford functionalized chromanes.

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YANG Group

Publications

116.Synthesis of Substituted Benzoxacycles via a Pd(II)-Catalyzed Intramolecular Arylation Reaction of Allylic Alcohols